Serveur d'exploration sur le cobalt au Maghreb

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Ethyl­enediammonium tetra­aqua­disulfato­cadmate

Identifieur interne : 000078 ( France/Analysis ); précédent : 000077; suivant : 000079

Ethyl­enediammonium tetra­aqua­disulfato­cadmate

Auteurs : Walid Rekik [Tunisie] ; Houcine Naïli [Tunisie] ; Tahar Mhiri [Tunisie] ; Thierry Bataille [France]

Source :

RBID : PMC:3200722

Abstract

The crystal structure of the title compound, [NH3(CH2)2NH3][Cd(SO4)2(H2O)4], consists of [Cd(SO4)2(H2O)4]2− anions that are built from octa­hedral Cd(H2O)4O2 and SO4 tetra­hedral units linked by corner sharing. The ethyl­ene­diamminium cations are linked to the anions via N—H⋯O hydrogen bonds. The asymmetric unit contains one-half of the compound, the other half being related to the first by an inversion centre. The crystal structure presents alternate stacking of the inorganic and organic layers along the crystallographic b axis. The structure cohesion and stability is further assured by O(water)—H⋯O hydrogen bonds.


Url:
DOI: 10.1107/S1600536811030005
PubMed: 22065822
PubMed Central: 3200722


Affiliations:


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PMC:3200722

Le document en format XML

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<p>The crystal structure of the title compound, [NH
<sub>3</sub>
(CH
<sub>2</sub>
)
<sub>2</sub>
NH
<sub>3</sub>
][Cd(SO
<sub>4</sub>
)
<sub>2</sub>
(H
<sub>2</sub>
O)
<sub>4</sub>
], consists of [Cd(SO
<sub>4</sub>
)
<sub>2</sub>
(H
<sub>2</sub>
O)
<sub>4</sub>
]
<sup>2−</sup>
anions that are built from octa­hedral Cd(H
<sub>2</sub>
O)
<sub>4</sub>
O
<sub>2</sub>
and SO
<sub>4</sub>
tetra­hedral units linked by corner sharing. The ethyl­ene­diamminium cations are linked to the anions
<italic>via</italic>
N—H⋯O hydrogen bonds. The asymmetric unit contains one-half of the compound, the other half being related to the first by an inversion centre. The crystal structure presents alternate stacking of the inorganic and organic layers along the crystallographic
<italic>b</italic>
axis. The structure cohesion and stability is further assured by O(water)—H⋯O hydrogen bonds.</p>
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